The collisional broadening of several rotational lines of SO2 perturbed by N2, O2, H2 and He has been investigated in a frequency range spanning from the millimeter-wave up to ~0.3 mm, at room temperature. In view of drawing conclusions over the J- and Ka-dependence trends of the pressure-broadening coefficients, for all perturbers, Q-type (DJ=0) transitions with 11 =< J =< 60 (with Ka=10) and 0 =< Ka =< 6 (with J=10) have been considered. While for all perturbers the observed trend suggests a weak maximum for J ~ 20, for the Ka dependence different trends are noted. For O2, H2, and He a small increase is noted by enlarging the Ka value, whereas a small decrease is observed for N2.
G. Cazzoli, C. Puzzarini (2012). N2-, O2-, H2-, and He-broadening of SO2 rotational lines in the mm-/submm-wave and THz frequency regions: The J and Ka dependence. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 113, 1051-1057 [10.1016/j.jqsrt.2012.01.011].
N2-, O2-, H2-, and He-broadening of SO2 rotational lines in the mm-/submm-wave and THz frequency regions: The J and Ka dependence
CAZZOLI, GABRIELE;PUZZARINI, CRISTINA
2012
Abstract
The collisional broadening of several rotational lines of SO2 perturbed by N2, O2, H2 and He has been investigated in a frequency range spanning from the millimeter-wave up to ~0.3 mm, at room temperature. In view of drawing conclusions over the J- and Ka-dependence trends of the pressure-broadening coefficients, for all perturbers, Q-type (DJ=0) transitions with 11 =< J =< 60 (with Ka=10) and 0 =< Ka =< 6 (with J=10) have been considered. While for all perturbers the observed trend suggests a weak maximum for J ~ 20, for the Ka dependence different trends are noted. For O2, H2, and He a small increase is noted by enlarging the Ka value, whereas a small decrease is observed for N2.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.