The collisional broadening of several rotational lines of SO2 perturbed by N2, O2, H2 and He has been investigated in a frequency range spanning from the millimeter-wave up to ~0.3 mm, at room temperature. In view of drawing conclusions over the J- and Ka-dependence trends of the pressure-broadening coefficients, for all perturbers, Q-type (DJ=0) transitions with 11 =< J =&lt; 60 (with Ka=10) and 0 =< Ka =&lt; 6 (with J=10) have been considered. While for all perturbers the observed trend suggests a weak maximum for J ~ 20, for the Ka dependence different trends are noted. For O2, H2, and He a small increase is noted by enlarging the Ka value, whereas a small decrease is observed for N2.

N2-, O2-, H2-, and He-broadening of SO2 rotational lines in the mm-/submm-wave and THz frequency regions: The J and Ka dependence / G. Cazzoli; C. Puzzarini. - In: JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER. - ISSN 0022-4073. - STAMPA. - 113:(2012), pp. 1051-1057. [10.1016/j.jqsrt.2012.01.011]

N2-, O2-, H2-, and He-broadening of SO2 rotational lines in the mm-/submm-wave and THz frequency regions: The J and Ka dependence

CAZZOLI, GABRIELE;PUZZARINI, CRISTINA
2012

Abstract

The collisional broadening of several rotational lines of SO2 perturbed by N2, O2, H2 and He has been investigated in a frequency range spanning from the millimeter-wave up to ~0.3 mm, at room temperature. In view of drawing conclusions over the J- and Ka-dependence trends of the pressure-broadening coefficients, for all perturbers, Q-type (DJ=0) transitions with 11 =< J =< 60 (with Ka=10) and 0 =< Ka =< 6 (with J=10) have been considered. While for all perturbers the observed trend suggests a weak maximum for J ~ 20, for the Ka dependence different trends are noted. For O2, H2, and He a small increase is noted by enlarging the Ka value, whereas a small decrease is observed for N2.
2012
N2-, O2-, H2-, and He-broadening of SO2 rotational lines in the mm-/submm-wave and THz frequency regions: The J and Ka dependence / G. Cazzoli; C. Puzzarini. - In: JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER. - ISSN 0022-4073. - STAMPA. - 113:(2012), pp. 1051-1057. [10.1016/j.jqsrt.2012.01.011]
G. Cazzoli; C. Puzzarini
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/116399
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