N-benzyl-tert-butyl nitroxide derivatives substituted at the aromatic ring form host-guest inclusion complexes with beta-and gamma-cyclodextrin. They were employed as probes to assess substituent effects on the geometry of the complex and on the kinetics of this complexation by combining EPR and (HNMR)-H-1 data
P. Franchi, C. Casati, E. Mezzina, M. Lucarini (2011). Kinetic control of the direction of inclusion of nitroxide radicals into cyclodextrins. ORGANIC & BIOMOLECULAR CHEMISTRY, 9, 6396-6401 [10.1039/c1ob05618b].
Kinetic control of the direction of inclusion of nitroxide radicals into cyclodextrins
FRANCHI, PAOLA;CASATI, COSTANZA;MEZZINA, ELISABETTA;LUCARINI, MARCO
2011
Abstract
N-benzyl-tert-butyl nitroxide derivatives substituted at the aromatic ring form host-guest inclusion complexes with beta-and gamma-cyclodextrin. They were employed as probes to assess substituent effects on the geometry of the complex and on the kinetics of this complexation by combining EPR and (HNMR)-H-1 dataFile in questo prodotto:
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