The pulsed supersonic-jet Fourier-transform microwave spectrum of the molecular complex of CF3Cl (freon-13) and water is effectively that of a symmetric top and shows that its two units (CF3Cl and H2O) are held together by an O···Cl halogen bond.
The Halogen Bond and Internal Dynamics in the Molecular Complex of CF3Cl and H2O / L.Evangelisti; G.Feng; P.Écija; E.J.Cocinero; F.Castaño; W.Caminati. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 50:(2011), pp. 7807-7810. [10.1002/anie.201102544]
The Halogen Bond and Internal Dynamics in the Molecular Complex of CF3Cl and H2O
EVANGELISTI, LUCA;FENG, GANG;CAMINATI, WALTHER
2011
Abstract
The pulsed supersonic-jet Fourier-transform microwave spectrum of the molecular complex of CF3Cl (freon-13) and water is effectively that of a symmetric top and shows that its two units (CF3Cl and H2O) are held together by an O···Cl halogen bond.File in questo prodotto:
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