The H - D isotopic substitution of the hydroxylic hydrogen participating in the O–H O hydrogen bond in the tertbutylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the O O distance of about 7 mA ˚ , underlying and sizing the associated Ubbelohde effect.
Sizing the Ubbelhode effect: The rotational spectrum of tert-butylalcohol dimer / S.Tang; I.Majerz; W.Caminati. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 13:(2011), pp. 9137-9139. [10.1039/c1cp20210c]
Sizing the Ubbelhode effect: The rotational spectrum of tert-butylalcohol dimer
CAMINATI, WALTHER
2011
Abstract
The H - D isotopic substitution of the hydroxylic hydrogen participating in the O–H O hydrogen bond in the tertbutylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the O O distance of about 7 mA ˚ , underlying and sizing the associated Ubbelohde effect.File in questo prodotto:
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