The H - D isotopic substitution of the hydroxylic hydrogen participating in the O–H O hydrogen bond in the tertbutylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the O O distance of about 7 mA ˚ , underlying and sizing the associated Ubbelohde effect.
S.Tang, I.Majerz, W.Caminati (2011). Sizing the Ubbelhode effect: The rotational spectrum of tert-butylalcohol dimer. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 13, 9137-9139 [10.1039/c1cp20210c].
Sizing the Ubbelhode effect: The rotational spectrum of tert-butylalcohol dimer
CAMINATI, WALTHER
2011
Abstract
The H - D isotopic substitution of the hydroxylic hydrogen participating in the O–H O hydrogen bond in the tertbutylalcohol dimer produces an increase of the B and C rotational constants, according to the shrinkage of the O O distance of about 7 mA ˚ , underlying and sizing the associated Ubbelohde effect.File in questo prodotto:
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