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EnglishThe addition of organolithium reagents to the trianglimine derived from (R,R)-1,2-diaminocyclohexane and terephthalaldehyde gave the corresponding trianglamine with complete stereocontrol and the R configuration of all six newly formed stereocenters. The structure of the hexaphenyl-substituted macrocyle was determined by X-ray crystallographic study. The new trianglamines were tested as ligands in enantioselective catalytic reactions.
| Titolo: | Stereoselective synthesis of ring C-hexasubstituted trianglamines | |
| Autore/i: | SAVOIA, DIEGO; GUALANDI, ANDREA; H. Stoeckli Evans | |
| Autore/i Unibo: | ||
| Anno: | 2010 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/c004873a | |
| Abstract: | The addition of organolithium reagents to the trianglimine derived from (R,R)-1,2-diaminocyclohexane and terephthalaldehyde gave the corresponding trianglamine with complete stereocontrol and the R configuration of all six newly formed stereocenters. The structure of the hexaphenyl-substituted macrocyle was determined by X-ray crystallographic study. The new trianglamines were tested as ligands in enantioselective catalytic reactions. | |
| Data prodotto definitivo in UGOV: | 2013-06-07 13:20:35 | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11585/103984
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