In dimethylether–HCl, the HCl group is tunnelling between the two lone pairs of the ether oxygen at a rate of 8182(7) MHz, through a barrier of 69 cm1, as deduced from the free jet millimetre wave absorption spectrum.
OTTAVIANI P., CAMINATI W., VELINO B., LOPEZ J.C. (2004). Tunnelling rate and barrier to the transfer of the protic group in dimethylether–HCl. CHEMICAL PHYSICS LETTERS, 394, 262-265 [10.1016/j.cplett.2004.07.010].
Tunnelling rate and barrier to the transfer of the protic group in dimethylether–HCl
OTTAVIANI, PAOLO;CAMINATI, WALTHER;VELINO, BIAGIO;
2004
Abstract
In dimethylether–HCl, the HCl group is tunnelling between the two lone pairs of the ether oxygen at a rate of 8182(7) MHz, through a barrier of 69 cm1, as deduced from the free jet millimetre wave absorption spectrum.File in questo prodotto:
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