In dimethylether–HCl, the HCl group is tunnelling between the two lone pairs of the ether oxygen at a rate of 8182(7) MHz, through a barrier of 69 cm1, as deduced from the free jet millimetre wave absorption spectrum.
Tunnelling rate and barrier to the transfer of the protic group in dimethylether–HCl / OTTAVIANI P.; CAMINATI W.; VELINO B.; LOPEZ J.C.. - In: CHEMICAL PHYSICS LETTERS. - ISSN 0009-2614. - STAMPA. - 394:(2004), pp. 262-265. [10.1016/j.cplett.2004.07.010]
Tunnelling rate and barrier to the transfer of the protic group in dimethylether–HCl
OTTAVIANI, PAOLO;CAMINATI, WALTHER;VELINO, BIAGIO;
2004
Abstract
In dimethylether–HCl, the HCl group is tunnelling between the two lone pairs of the ether oxygen at a rate of 8182(7) MHz, through a barrier of 69 cm1, as deduced from the free jet millimetre wave absorption spectrum.File in questo prodotto:
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