The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.
S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini (2011). C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature. INORGANIC CHEMISTRY, 50, 3846-3848 [10.1021/ic2001199].
C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature
ZACCHINI, STEFANO
2011
Abstract
The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.File in questo prodotto:
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