The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.
Titolo: | C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature |
Autore/i: | S. Dolci; F. Marchetti; G. Pampaloni; ZACCHINI, STEFANO |
Autore/i Unibo: | |
Anno: | 2011 |
Rivista: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ic2001199 |
Abstract: | The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5. |
Data prodotto definitivo in UGOV: | 2013-05-31 17:21:21 |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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