The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.
C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature / S. Dolci; F. Marchetti; G. Pampaloni; S. Zacchini. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 50:(2011), pp. 3846-3848. [10.1021/ic2001199]
C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature
ZACCHINI, STEFANO
2011
Abstract
The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.File in questo prodotto:
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