Molecular-level resolution was achieved for the detection of short-chain alcohols in the vapor phase using a fluorescent cavitand sensor. The transduction mechanism, activated exclusively by the complexation mode, is provided by the change of the electronic density on the fluorophore caused by the formation of an intracavity hydrogen bond between the cavitand P=O and the alcohol OH group.
F. Maffei, P. Betti, D. Genovese, M. Montalti, L. Prodi, R. De Zorzi, et al. (2011). Highly Selective Chemical Vapor Sensing by Molecular Recognition: Specific Detection of C-1-C-4 Alcohols with a Fluorescent Phosphonate Cavitand. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 50, 4654-4657 [10.1002/anie.201100738].
Highly Selective Chemical Vapor Sensing by Molecular Recognition: Specific Detection of C-1-C-4 Alcohols with a Fluorescent Phosphonate Cavitand
GENOVESE, DAMIANO;MONTALTI, MARCO;PRODI, LUCA;
2011
Abstract
Molecular-level resolution was achieved for the detection of short-chain alcohols in the vapor phase using a fluorescent cavitand sensor. The transduction mechanism, activated exclusively by the complexation mode, is provided by the change of the electronic density on the fluorophore caused by the formation of an intracavity hydrogen bond between the cavitand P=O and the alcohol OH group.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
