The partial reduction of nitroarenes with hydroxides in alcoholic media is a venerable yet very direct approach to the synthesis of symmetrical azoxyarenes. Herein, the first application of this method to nitropyridines is disclosed, presenting its adaptation with these challenging but important substrates.
Caruana, L., Pistilli, D., Bussolari, A., Toderi, E., Nalin, A., Osti, S., et al. (2025). Reductive Synthesis of Azoxypyridines from Nitropyridines Using Hydroxides in Alcoholic Media. SYNTHESIS, 57(04), 846-854 [10.1055/a-2492-3780].
Reductive Synthesis of Azoxypyridines from Nitropyridines Using Hydroxides in Alcoholic Media
Caruana, Lorenzo;Bussolari, Alessio;Santarelli, Nicolò;Fochi Mariafrancesca;Bernardi Luca
2025
Abstract
The partial reduction of nitroarenes with hydroxides in alcoholic media is a venerable yet very direct approach to the synthesis of symmetrical azoxyarenes. Herein, the first application of this method to nitropyridines is disclosed, presenting its adaptation with these challenging but important substrates.File in questo prodotto:
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