The reaction of dillyltin dibromide, readily prepared from allyl bromide and tin powder, with aldehydes in the presence of monosodium-(+)-diethyl tartrate affords the corresponding homoallylic alcohols in good yields with enantiomeric excesses in the range 42 to 71%. © 1988.
Boga, C., Savoia, D., Tagliavini, E., Trombini, C., Umani-Ronchi, A. (1988). Synthesis of chiral homoallylic alcohols from aldehydes and diallyltin dibromide in the presence of monosodium-(+)-diethyl tartrate. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 353(2), 177-183 [10.1016/0022-328X(88)83061-4].
Synthesis of chiral homoallylic alcohols from aldehydes and diallyltin dibromide in the presence of monosodium-(+)-diethyl tartrate
Boga C.;Savoia D.;Tagliavini E.;Trombini C.;Umani-Ronchi A.
1988
Abstract
The reaction of dillyltin dibromide, readily prepared from allyl bromide and tin powder, with aldehydes in the presence of monosodium-(+)-diethyl tartrate affords the corresponding homoallylic alcohols in good yields with enantiomeric excesses in the range 42 to 71%. © 1988.File in questo prodotto:
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