The reactions of methylcopper- and diemthylcuprate-boron trifluoride reagents with aldimines derived from (S)-1-phenylethylamine afford with good diastereoselectivity (S,S)-amines from aromatic imines, but the (R,S)-amine from an aliphatic imine. © 1990.
Boga, C., Savoia, D., Umani-Ronchi, A. (1990). Diastereoselective addition of methylcopper- and diemthylcuprate-boron trifluoride reagents to (S)-(N-alkylidine)-1-phenylethylamines. TETRAHEDRON-ASYMMETRY, 1(5), 291-294 [10.1016/S0957-4166(00)86316-8].
Diastereoselective addition of methylcopper- and diemthylcuprate-boron trifluoride reagents to (S)-(N-alkylidine)-1-phenylethylamines
Boga C.;Savoia D.;Umani-Ronchi A.
1990
Abstract
The reactions of methylcopper- and diemthylcuprate-boron trifluoride reagents with aldimines derived from (S)-1-phenylethylamine afford with good diastereoselectivity (S,S)-amines from aromatic imines, but the (R,S)-amine from an aliphatic imine. © 1990.File in questo prodotto:
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