Optically pure, C2-symmetric N,N,N-ligands containing the pyridine ring with two substituents at C2 and C6 both incorporating one aziridine ring have been prepared by a three-step sequence and overall high diastereoselectivity. These new compounds can act as di- or tridentate ligands towards metallic species, which are active catalysts in enantioselective transformations.
C. Fiorelli, D. Savoia, A. Gualandi (2005). Synthesis of C2-symmetric (N,N,N) ligands containing pyridine and aziridine rings. s.l : s.n.
Synthesis of C2-symmetric (N,N,N) ligands containing pyridine and aziridine rings
FIORELLI, CLAUDIO;SAVOIA, DIEGO;GUALANDI, ANDREA
2005
Abstract
Optically pure, C2-symmetric N,N,N-ligands containing the pyridine ring with two substituents at C2 and C6 both incorporating one aziridine ring have been prepared by a three-step sequence and overall high diastereoselectivity. These new compounds can act as di- or tridentate ligands towards metallic species, which are active catalysts in enantioselective transformations.File in questo prodotto:
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