The addition of organolithium reagents to the trianglimine derived from the condensation of enantiopure trans-1,2-diaminocyclohexane and terephthalaldehyde gives the corresponding trianglamine with complete stereoselectivity. The new trianglamine were useful as chiral solvating agents for the determination of the enantiomeric puruty of chiral carboxylic acids by NMR techiques.
D. Savoia, A. Gualandi, H. Stoeckli-Evans, L. Cerisoli (2010). Stereoselective synthesis and applications of ring C-hexasubstituted trianglamines. s.l : Società Chimica Italiana.
Stereoselective synthesis and applications of ring C-hexasubstituted trianglamines
SAVOIA, DIEGO;GUALANDI, ANDREA;CERISOLI, LUCIA
2010
Abstract
The addition of organolithium reagents to the trianglimine derived from the condensation of enantiopure trans-1,2-diaminocyclohexane and terephthalaldehyde gives the corresponding trianglamine with complete stereoselectivity. The new trianglamine were useful as chiral solvating agents for the determination of the enantiomeric puruty of chiral carboxylic acids by NMR techiques.File in questo prodotto:
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