The invention relates to a process for the preparation of 1-(1,3-benzodioxol-5-yl)-l-propanone comprising the step of reacting 3,4-dimethylendioxybenzene with propionic anhydride in the presence of a bulk or supported catalyst, being said catalyst selected from the group of a sulphonated cross-linked divinylbenzene resin, a sulphonated cross-linked divinylbenzene resin partially exchanged with iron, zinc or gallium, a perfhtorinated sulphonic resin, and a perfhtorinated sulphonic resin partially exchanged with iron, zinc or gallium, wherein said catalyst has an average particle size from 1 pm to 300 pm, preferably from 1 pm to 180 pm, more preferably from 1 pm to 100 pm as measured with DLS (Dynamic light scattering) or a granulometer. The process is advantageously carried out at stoichiometric ratio between the reagents and with a continuos process.

PROCESS FOR THE PREPARATION OF 3,4-METHYLENEDIOXYPROPIOPHENONE / LUCARELLI Carlo; TABANELLI Tommaso; VACCARI Angelo; EBERLE Martina; MARCHIORO Carla; CAMPANATI Matteo; BILLI Stefano; GUERRINI Alberto; SCHIAROLI Nicola.. - (2021).

PROCESS FOR THE PREPARATION OF 3,4-METHYLENEDIOXYPROPIOPHENONE

LUCARELLI Carlo;TABANELLI Tommaso;VACCARI Angelo;EBERLE Martina;SCHIAROLI Nicola.
2021

Abstract

The invention relates to a process for the preparation of 1-(1,3-benzodioxol-5-yl)-l-propanone comprising the step of reacting 3,4-dimethylendioxybenzene with propionic anhydride in the presence of a bulk or supported catalyst, being said catalyst selected from the group of a sulphonated cross-linked divinylbenzene resin, a sulphonated cross-linked divinylbenzene resin partially exchanged with iron, zinc or gallium, a perfhtorinated sulphonic resin, and a perfhtorinated sulphonic resin partially exchanged with iron, zinc or gallium, wherein said catalyst has an average particle size from 1 pm to 300 pm, preferably from 1 pm to 180 pm, more preferably from 1 pm to 100 pm as measured with DLS (Dynamic light scattering) or a granulometer. The process is advantageously carried out at stoichiometric ratio between the reagents and with a continuos process.
2021
WO 2022/162223 Al
PROCESS FOR THE PREPARATION OF 3,4-METHYLENEDIOXYPROPIOPHENONE / LUCARELLI Carlo; TABANELLI Tommaso; VACCARI Angelo; EBERLE Martina; MARCHIORO Carla; CAMPANATI Matteo; BILLI Stefano; GUERRINI Alberto; SCHIAROLI Nicola.. - (2021).
LUCARELLI Carlo; TABANELLI Tommaso; VACCARI Angelo; EBERLE Martina; MARCHIORO Carla; CAMPANATI Matteo; BILLI Stefano; GUERRINI Alberto; SCHIAROLI Nicola.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/898393
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