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EnglishThe literature up to July 2008 dealing with catalytic enantioselective FC alkylation of aromatic compounds with nitroalkenes has been reviewed. Both metal-mediated and organocatalysis have been employed leading to a vast array of enantiomerically pure compounds most of them of interest in medicinal chemistry. An insight into the mechanism of the various catalytic methodologies is provided aimed at providing a rationale for the reactions treated.
| Titolo: | Nitroalkenes |
| Autore/i: | BERNARDI, LUCA; RICCI, ALFREDO MARCO |
| Autore/i Unibo: | |
| Anno: | 2009 |
| Titolo del libro: | Catalytic Asymmetric Friedel-Crafts Alkylations |
| Pagina iniziale: | 67 |
| Pagina finale: | 99 |
| Abstract: | The literature up to July 2008 dealing with catalytic enantioselective FC alkylation of aromatic compounds with nitroalkenes has been reviewed. Both metal-mediated and organocatalysis have been employed leading to a vast array of enantiomerically pure compounds most of them of interest in medicinal chemistry. An insight into the mechanism of the various catalytic methodologies is provided aimed at providing a rationale for the reactions treated. |
| Data prodotto definitivo in UGOV: | 3-feb-2010 |
| Appare nelle tipologie: | 2.01 Capitolo / saggio in libro |
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