Reduction reactions of CO2using chemicals obtained from renewable energy sources (as for example, dihydrogen obtained using renewable-issued electricity) or using directly renewable energy sources can contribute to store and use renewable energies in our current infrastructures. Rh-based catalysts have been playing a key role in the field of CO2reduction. From its very first application as homogeneous catalyst to now, several Rh-based catalytic systems have been successfully tested. This chapter gives the reader an overview as well as a mechanistic insight where possible into the Rh-catalysed CO2reduction reductions: production of formic acid and higher carboxylic acids with homogeneous catalysts, methane, CO and various oxygenated compounds via heterogeneous catalysis, and various products by means of electro- and photocatalysis.
CO2reduction reactions by rhodium-based catalysts / Bonincontro, Danilo; Quadrelli, Elsje Alessandra. - STAMPA. - 61:(2018), pp. 263-282. [10.1007/3418_2016_172]
CO2reduction reactions by rhodium-based catalysts
BONINCONTRO, DANILO;
2018
Abstract
Reduction reactions of CO2using chemicals obtained from renewable energy sources (as for example, dihydrogen obtained using renewable-issued electricity) or using directly renewable energy sources can contribute to store and use renewable energies in our current infrastructures. Rh-based catalysts have been playing a key role in the field of CO2reduction. From its very first application as homogeneous catalyst to now, several Rh-based catalytic systems have been successfully tested. This chapter gives the reader an overview as well as a mechanistic insight where possible into the Rh-catalysed CO2reduction reductions: production of formic acid and higher carboxylic acids with homogeneous catalysts, methane, CO and various oxygenated compounds via heterogeneous catalysis, and various products by means of electro- and photocatalysis.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
