Imidazolininone organocatalysts (MacMillan catalysts) are one of the most effective catalysts, used in many interesting organocatalytic reactions. Their robustness, easy preparation from amino acids, and widespread use, make them one of the most powerful catalysts for general enantioselective transformations. The imidazolidinone catalysts promote new reaction modes in organocatalysis, such as SOMO activation and enantioselective photocatalytic reactions. Herein, the key principles underpinning their functionality and their reported use are summarised.

Cozzi, P.G., Gualandi, A., Mengozzi, L., Wilson, C.M. (2015). Chapter 18. Imidazolidinones as Asymmetric Organocatalysts. Cambridge : RSC Publishing [10.1039/9781782626435-00164].

Chapter 18. Imidazolidinones as Asymmetric Organocatalysts

COZZI, PIER GIORGIO;GUALANDI, ANDREA;MENGOZZI, LUCA;
2015

Abstract

Imidazolininone organocatalysts (MacMillan catalysts) are one of the most effective catalysts, used in many interesting organocatalytic reactions. Their robustness, easy preparation from amino acids, and widespread use, make them one of the most powerful catalysts for general enantioselective transformations. The imidazolidinone catalysts promote new reaction modes in organocatalysis, such as SOMO activation and enantioselective photocatalytic reactions. Herein, the key principles underpinning their functionality and their reported use are summarised.
2015
Sustainable Catalysis : Without Metals or Other Endangered Elements, Part 2
164
195
Cozzi, P.G., Gualandi, A., Mengozzi, L., Wilson, C.M. (2015). Chapter 18. Imidazolidinones as Asymmetric Organocatalysts. Cambridge : RSC Publishing [10.1039/9781782626435-00164].
Cozzi, Pier Giorgio; Gualandi, Andrea; Mengozzi, Luca; Wilson, Claire Margaret
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/545865
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