We have recently reported some new mono and dinuclear Ru(II) polypyridyl complexes containing various 5-substituted tetrazolate ligands which were shown to act as efficient ElectroChemiLuminescence (ECL) luminophores [1]. In light of these interesting results, we now report a series of new polypyridyl Ru(II) complexes in which thienyl-tetrazole derivatives as well chelating tetrazolates are introduced in the coordination sphere of the metal centres. A complete survey of the main coordinative, electrochemical and structural features of these complexes will be presented. 1. Stagni, S.; Palazzi, A.; Zacchini, S.; Ballarin, B.; Marcaccio, M.; Paolucci, F.; Bruno, C.; Monari, M.; Carano, M.; Bard, A.J. Inorg. Chem. 2006, 45, 695-709.
A. Palazzi, S. Stagni (2006). New Polypyridyl Ruthenium (II) Complexes with tetrazolate ligands. s.l : Società Chimica Italiana.
New Polypyridyl Ruthenium (II) Complexes with tetrazolate ligands
PALAZZI, ANTONIO;STAGNI, STEFANO
2006
Abstract
We have recently reported some new mono and dinuclear Ru(II) polypyridyl complexes containing various 5-substituted tetrazolate ligands which were shown to act as efficient ElectroChemiLuminescence (ECL) luminophores [1]. In light of these interesting results, we now report a series of new polypyridyl Ru(II) complexes in which thienyl-tetrazole derivatives as well chelating tetrazolates are introduced in the coordination sphere of the metal centres. A complete survey of the main coordinative, electrochemical and structural features of these complexes will be presented. 1. Stagni, S.; Palazzi, A.; Zacchini, S.; Ballarin, B.; Marcaccio, M.; Paolucci, F.; Bruno, C.; Monari, M.; Carano, M.; Bard, A.J. Inorg. Chem. 2006, 45, 695-709.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
