Over the past years, the investigation of the coordination chemistry of tetrazolate compounds has been the primary thrust of our research program. The scientific activity was initially devoted to the study of a series of mono and dinuclear Fe(II) organometallic species containing 5-aryl tetrazolates as mono coordinating ligands and successively focused to the preparation of the analogous Ru(II) polypyridyl complexes, which have shown interesting electrochemical properties and highly efficient ElectroChemiLuminescence (ECL) performances. In light of these features, we extended our studies to a wide range of differently substituted tetrazolates to constitute a new family of tetrazole-based Ru(II) polypyridyl complexes. As the latest development of our research, we now report the synthesis and the characterization of some new mono and dinuclear Ir(III) cyclometalated diimine complexes containing chelating tetrazolates. Some preliminary accounts about their electrochemical and photophysical properties will also be discussed.

Chelating Tetrazolates as Ligands for Ir(III) Cyclometalated Complexes / A. Palazzi; S.Stagni. - STAMPA. - (2006), pp. 32-32. (Intervento presentato al convegno VII Congresso del Gruppo Interdivisionale di Chimica Organometallica tenutosi a Parma nel 9-12 luglio 2006).

Chelating Tetrazolates as Ligands for Ir(III) Cyclometalated Complexes

PALAZZI, ANTONIO;STAGNI, STEFANO
2006

Abstract

Over the past years, the investigation of the coordination chemistry of tetrazolate compounds has been the primary thrust of our research program. The scientific activity was initially devoted to the study of a series of mono and dinuclear Fe(II) organometallic species containing 5-aryl tetrazolates as mono coordinating ligands and successively focused to the preparation of the analogous Ru(II) polypyridyl complexes, which have shown interesting electrochemical properties and highly efficient ElectroChemiLuminescence (ECL) performances. In light of these features, we extended our studies to a wide range of differently substituted tetrazolates to constitute a new family of tetrazole-based Ru(II) polypyridyl complexes. As the latest development of our research, we now report the synthesis and the characterization of some new mono and dinuclear Ir(III) cyclometalated diimine complexes containing chelating tetrazolates. Some preliminary accounts about their electrochemical and photophysical properties will also be discussed.
2006
Co.G.I.C.O. 2006 Atti VII Congresso del Gruppo Interdivisionale di Chimica Organometallica
32
32
Chelating Tetrazolates as Ligands for Ir(III) Cyclometalated Complexes / A. Palazzi; S.Stagni. - STAMPA. - (2006), pp. 32-32. (Intervento presentato al convegno VII Congresso del Gruppo Interdivisionale di Chimica Organometallica tenutosi a Parma nel 9-12 luglio 2006).
A. Palazzi; S.Stagni
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/35652
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact