The radical reaction of alkanethiols with tert-butyl isocyanide in boiling benzene gives rise to intermediate thioimidoyls radicals which undergo easy fragmentation yielding tert-butyl isothiocyanate and corresponding alkyl radicals. These reactions allow a new protocol for the generation of alkyl radicals under tin-free conditions.
Thioimidoyl Radicals as a Novel Tin-Free Source of Alkyl Radicals / L. Benati; R. Leardini; M. Minozzi; D. Nanni; R. Scialpi; P. Spagnolo; S. Strazzari; J. C. Walton; G. Zanardi. - STAMPA. - (2004), pp. P-64-P-64. (Intervento presentato al convegno International Symposium on Organic Free Radicals (ISOFR 9th) tenutosi a Porto-Vecchio (France) nel 6-11 June 2004).
Thioimidoyl Radicals as a Novel Tin-Free Source of Alkyl Radicals
BENATI, MARIA LUISA;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;STRAZZARI, SAMANTHA;ZANARDI, GIUSEPPE
2004
Abstract
The radical reaction of alkanethiols with tert-butyl isocyanide in boiling benzene gives rise to intermediate thioimidoyls radicals which undergo easy fragmentation yielding tert-butyl isothiocyanate and corresponding alkyl radicals. These reactions allow a new protocol for the generation of alkyl radicals under tin-free conditions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.