The radical reaction of alkanethiols with tert-butyl isocyanide in boiling benzene gives rise to intermediate thioimidoyls radicals which undergo easy fragmentation yielding tert-butyl isothiocyanate and corresponding alkyl radicals. These reactions allow a new protocol for the generation of alkyl radicals under tin-free conditions.
Thioimidoyl Radicals as a Novel Tin-Free Source of Alkyl Radicals
BENATI, MARIA LUISA;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;STRAZZARI, SAMANTHA;ZANARDI, GIUSEPPE
2004
Abstract
The radical reaction of alkanethiols with tert-butyl isocyanide in boiling benzene gives rise to intermediate thioimidoyls radicals which undergo easy fragmentation yielding tert-butyl isothiocyanate and corresponding alkyl radicals. These reactions allow a new protocol for the generation of alkyl radicals under tin-free conditions.File in questo prodotto:
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