This paper deals with an investigation of hexagonal W-V-Nb-O and W-V-Mo-O bronzes as catalysts for the one-pot oxidehydration of glycerol into acrylic acid. In a previous work, we reported a study on bi-component systems W-V-O bronze that allowed us to obtain a 25% acrylic acid selectivity; in the current work, the incorporation of Nb or Mo in the tri-component bronze structure allowed us to tune the acid and redox properties of the catalyst, so as to study their influence on the overall reaction scheme.
F. Basile, F. Cavani, A. Chieregato, P. Concepcion, G. Liosi, J.M. Lopez Nieto, et al. (2012). Glycerol oxidehydration into acrolein and acrylic acid over W/V/Nb bronzes with hexagonal structure. Hamburg : DGMK Tagungsbericht German Society for Petroleum.
Glycerol oxidehydration into acrolein and acrylic acid over W/V/Nb bronzes with hexagonal structure
BASILE, FRANCESCO;CAVANI, FABRIZIO;CHIEREGATO, ALESSANDRO;LIOSI, GIUSEPPE;TREVISANUT, CRISTIAN
2012
Abstract
This paper deals with an investigation of hexagonal W-V-Nb-O and W-V-Mo-O bronzes as catalysts for the one-pot oxidehydration of glycerol into acrylic acid. In a previous work, we reported a study on bi-component systems W-V-O bronze that allowed us to obtain a 25% acrylic acid selectivity; in the current work, the incorporation of Nb or Mo in the tri-component bronze structure allowed us to tune the acid and redox properties of the catalyst, so as to study their influence on the overall reaction scheme.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
