The present invention relates to a process for producing polyhydroxyalkanoate oligomers andlor polymers of re-duced molecular weight, which comprises reacting at least one polyhydroxyalkanoate (PHA) with at least one carbonate saltata temperature of from 50°C to 300°C, preferably from l20°C to 200°C. The above reaction allows a controlled degradation of the PHA chains which yields oligomers andlor polymers having a controlled molecular weight, which can be modulated in view ofthe specific application for which the oligomers andlor polymers are intended. Moreover, during the reaction carbon dioxide evolves which produces a foamed material which can be easily processed on an industriai scale. Additionally, the above oligomers andlor polymers, having an end-group bearing a double band C=C, particularly a crotonate end-group for PHB, can be subjected to sub-sequent modifications to obtain a wide variety of functional end-groups, for instance carboxyl, carboxylate, hydroxyl, dihydroxyl, oxirane ring, halogen atom. Moreover, the low molecular weight PHAs may be used in the area of controlled delivery systems in agro-chemistry, in the cosmetic industry, in medicine in the form of nano-or microspheres, in household products and in coating systems.
PROCESS FOR CONTROLLED DEGRADATION OF POLYHYDROXYALKANOATES AND PRODUCTS OBTAINABLE THEREFROM
SCANDOLA, MARIASTELLA;MAZZOCCHETTI, LAURA;FOCARETE, MARIA LETIZIA;
2010
Abstract
The present invention relates to a process for producing polyhydroxyalkanoate oligomers andlor polymers of re-duced molecular weight, which comprises reacting at least one polyhydroxyalkanoate (PHA) with at least one carbonate saltata temperature of from 50°C to 300°C, preferably from l20°C to 200°C. The above reaction allows a controlled degradation of the PHA chains which yields oligomers andlor polymers having a controlled molecular weight, which can be modulated in view ofthe specific application for which the oligomers andlor polymers are intended. Moreover, during the reaction carbon dioxide evolves which produces a foamed material which can be easily processed on an industriai scale. Additionally, the above oligomers andlor polymers, having an end-group bearing a double band C=C, particularly a crotonate end-group for PHB, can be subjected to sub-sequent modifications to obtain a wide variety of functional end-groups, for instance carboxyl, carboxylate, hydroxyl, dihydroxyl, oxirane ring, halogen atom. Moreover, the low molecular weight PHAs may be used in the area of controlled delivery systems in agro-chemistry, in the cosmetic industry, in medicine in the form of nano-or microspheres, in household products and in coating systems.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
