The pure rotational spectra of 13-C2HD and 12-C2HD were detected in the range 114-687 GHz. Lines belonging to the ground vibrational state were observed from J”=1 to J”=11. Several absorption lines were also detected in v4=1 (Π), v5=1 (Π), v4=2 (Σ and Δ), v5=2 (Σ and Δ), v4=v5=1 (Σ−, Σ+ and Δ), v4=3 (Π and Φ) and v5=3 (Π and Φ). The transitions detected in this work were fitted together with all the infrared lines available in literature for the bending states. The global fits allowed a very accurate determination of the spectroscopic parameters of these molecules.
Dore L., Degli Esposti C., Fusina L., Tamassia F., Di Lonardo G. (2012). The Rotational Spectrum of 13C2HD and 12C2HD in the Ground and Excited Bending States: a Global Analysis.. PRAGUE : ICT Prague Press.
The Rotational Spectrum of 13C2HD and 12C2HD in the Ground and Excited Bending States: a Global Analysis.
DORE, LUCA;DEGLI ESPOSTI, CLAUDIO;FUSINA, LUCIANO;TAMASSIA, FILIPPO;DI LONARDO, GIANFRANCO
2012
Abstract
The pure rotational spectra of 13-C2HD and 12-C2HD were detected in the range 114-687 GHz. Lines belonging to the ground vibrational state were observed from J”=1 to J”=11. Several absorption lines were also detected in v4=1 (Π), v5=1 (Π), v4=2 (Σ and Δ), v5=2 (Σ and Δ), v4=v5=1 (Σ−, Σ+ and Δ), v4=3 (Π and Φ) and v5=3 (Π and Φ). The transitions detected in this work were fitted together with all the infrared lines available in literature for the bending states. The global fits allowed a very accurate determination of the spectroscopic parameters of these molecules.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
