Optically pure, C2-symmetric N,N,N-ligands containing the pyridine ring with two substituents at C2 and C6 both incorporating one aziridine ring have been prepared by a three-step sequence and overall high diastereoselectivity. These new compounds can act as di- or tridentate ligands towards metallic species, which are active catalysts in enantioselective transformations.
Synthesis of C2-symmetric (N,N,N) ligands containing pyridine and aziridine rings / C. Fiorelli; D. Savoia; A. Gualandi. - STAMPA. - (2005), pp. 54-54. (Intervento presentato al convegno 5th International School of Organometallic Chemistry tenutosi a Camerino nel 10-14 settembre 2005).
Synthesis of C2-symmetric (N,N,N) ligands containing pyridine and aziridine rings
FIORELLI, CLAUDIO;SAVOIA, DIEGO;GUALANDI, ANDREA
2005
Abstract
Optically pure, C2-symmetric N,N,N-ligands containing the pyridine ring with two substituents at C2 and C6 both incorporating one aziridine ring have been prepared by a three-step sequence and overall high diastereoselectivity. These new compounds can act as di- or tridentate ligands towards metallic species, which are active catalysts in enantioselective transformations.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
