The addition of organolithium reagents to the trianglimine derived from the condensation of enantiopure trans-1,2-diaminocyclohexane and terephthalaldehyde gives the corresponding trianglamine with complete stereoselectivity. The new trianglamine were useful as chiral solvating agents for the determination of the enantiomeric puruty of chiral carboxylic acids by NMR techiques.
Stereoselective synthesis and applications of ring C-hexasubstituted trianglamines / D. Savoia; A. Gualandi; H. Stoeckli-Evans; L. Cerisoli. - STAMPA. - (2010), pp. P19-P19. (Intervento presentato al convegno XXXIII Convegno Nazionale della Divisione di Chimica Organica tenutosi a S. Benedetto del Tronto (AP) nel 12-16 settembre 2010).
Stereoselective synthesis and applications of ring C-hexasubstituted trianglamines
SAVOIA, DIEGO;GUALANDI, ANDREA;CERISOLI, LUCIA
2010
Abstract
The addition of organolithium reagents to the trianglimine derived from the condensation of enantiopure trans-1,2-diaminocyclohexane and terephthalaldehyde gives the corresponding trianglamine with complete stereoselectivity. The new trianglamine were useful as chiral solvating agents for the determination of the enantiomeric puruty of chiral carboxylic acids by NMR techiques.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
