Partially deprotonated inorg. oxoanions derived from sulfuric and phosphoric acids were used to assemble organometallic cations in inorg.-organometallic hybrid systems. The organometallic sandwich cations [(h5-C5H5)2Co]+, [(h5-C5Me5)2Co]+ and [(h5-C5Me5)2Fe]+ were used because they do not interfere with H bonding formation forcing self-assembling of the inorg. acids anions HSO4- and H2PO4- into H bonded mono- and bi-dimensional networks
Crystal synthesis of hybrid organometallic-inorganic hydrogen bonded salts of acid oxoanions / D. Braga; M. Curzi; L. Maini; M. Polito; F. Grepioni,. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - -:(2004), pp. 2432-2437. [10.1039/b400667d]
Crystal synthesis of hybrid organometallic-inorganic hydrogen bonded salts of acid oxoanions.
BRAGA, DARIO;CURZI, MARCO;MAINI, LUCIA;POLITO, MARCO;GREPIONI, FABRIZIA
2004
Abstract
Partially deprotonated inorg. oxoanions derived from sulfuric and phosphoric acids were used to assemble organometallic cations in inorg.-organometallic hybrid systems. The organometallic sandwich cations [(h5-C5H5)2Co]+, [(h5-C5Me5)2Co]+ and [(h5-C5Me5)2Fe]+ were used because they do not interfere with H bonding formation forcing self-assembling of the inorg. acids anions HSO4- and H2PO4- into H bonded mono- and bi-dimensional networksI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
