Based on mol. mechanics, Yang photocyclization of a-1-norbornylacetophenone derivs. in the cryst. state was engineered through methylation adjacent to the carbonyl group, thus changing the conformation in the crystal and leading to enhanced diastereo- and enantioselectivity.

Molecular mechanics-assisted crystal engineering of solid state photoreactions: application to the Yang photocyclization of a-1-norbornylacetophenone derivatives.

BRAGA, DARIO;MAINI, LUCIA;
2005

Abstract

Based on mol. mechanics, Yang photocyclization of a-1-norbornylacetophenone derivs. in the cryst. state was engineered through methylation adjacent to the carbonyl group, thus changing the conformation in the crystal and leading to enhanced diastereo- and enantioselectivity.
2005
M. Botoshansky; D. Braga; M. Kaftory; L. Maini; B. O. Patrick; J. R. Scheffer; K. Wang,
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/9258
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