Ester-functionalized poly(3-alkylthienylene)s were obtained by chemical oxidation with FeCl3. Substituents with both different total length and different distance of the ester group from the thiophene ring were examined. The main reaction solvent studied was chloroform which gave polymers with high molecular weight and incomplete conversion of the monomer. Some polymers were synthesized with a new procedure involving the precipitation of FeCl3 from a saturated nitromethane solution by a tetrachloride solution of the monomer. In this way, lower molecular weights and complete monomer conversion were obtained. The effect of different substituent groups on the polymer microstructure was examined using 1H NMR spectroscopy. With both polymerization procedures, the regioregularity and absorption maximum in the visible spectrum increase with increasing length of the oligomethylenic spacer between thiophene ring and ester group. © 1995.
Ester-functionalized poly(3-alkylthienylene)s: substituent effects on the polymerization with FeCl3 / Costa Bizzarri P.; Andreani F.; Della Casa C.; Lanzi M.; Salatelli E.. - In: SYNTHETIC METALS. - ISSN 0379-6779. - STAMPA. - 75:2(1995), pp. 141-147. [10.1016/0379-6779(95)03401-5]
Ester-functionalized poly(3-alkylthienylene)s: substituent effects on the polymerization with FeCl3
Lanzi M.;Salatelli E.
1995
Abstract
Ester-functionalized poly(3-alkylthienylene)s were obtained by chemical oxidation with FeCl3. Substituents with both different total length and different distance of the ester group from the thiophene ring were examined. The main reaction solvent studied was chloroform which gave polymers with high molecular weight and incomplete conversion of the monomer. Some polymers were synthesized with a new procedure involving the precipitation of FeCl3 from a saturated nitromethane solution by a tetrachloride solution of the monomer. In this way, lower molecular weights and complete monomer conversion were obtained. The effect of different substituent groups on the polymer microstructure was examined using 1H NMR spectroscopy. With both polymerization procedures, the regioregularity and absorption maximum in the visible spectrum increase with increasing length of the oligomethylenic spacer between thiophene ring and ester group. © 1995.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
