The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988.
Thiiranes: One-pot synthesis from alkenes, and catalytic desulphurization
Capozzi F.;
1988
Abstract
The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988.File in questo prodotto:
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