The preparation of cobalt hexacyanoferrate nanoparticles–poly(methyl methacrylate) (CoHCF–PMMA) composites are described together with their characterization and thermochromic properties. CoHCF nanoparticles – investigated by dynamic light scattering – were prepared by optimizing solvent composition and temperature to obtain nanoparticles with a reduced degree of aggregation. The nanoparticles were embedded in a PMMA matrix to obtain a transparent coloured composite which was studied by transmission electron microscopy. The nanoparticle chromic features, enhanced by their reduced sizes, were investigated by UV–vis and FT-IR spectroscopy.
Cobalt hexacyanoferrate – poly(methylmetacrilate) composite: synthesis and characterization / A. Zanotto; R. Matassa; M. L. Saladino; M. Berrettoni; M. Giorgetti; S. Zamponi; E. Caponetti. - In: MATERIALS CHEMISTRY AND PHYSICS. - ISSN 0254-0584. - STAMPA. - 120:(2010), pp. 118-122. [10.1016/j.matchemphys.2009.10.032]
Cobalt hexacyanoferrate – poly(methylmetacrilate) composite: synthesis and characterization
BERRETTONI, MARIO;GIORGETTI, MARCO;
2010
Abstract
The preparation of cobalt hexacyanoferrate nanoparticles–poly(methyl methacrylate) (CoHCF–PMMA) composites are described together with their characterization and thermochromic properties. CoHCF nanoparticles – investigated by dynamic light scattering – were prepared by optimizing solvent composition and temperature to obtain nanoparticles with a reduced degree of aggregation. The nanoparticles were embedded in a PMMA matrix to obtain a transparent coloured composite which was studied by transmission electron microscopy. The nanoparticle chromic features, enhanced by their reduced sizes, were investigated by UV–vis and FT-IR spectroscopy.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.