Laser-induced in situ synthesis of Pd and Pt nanoparticles on polymer films

Abstract: We present the localized in situ formation of Pd and Pt nanoparticles embedded in chitosan solid films. This is achieved by the photo-induced reduction of metallic precursors, previously incorporated in chitosan films, through controlled UV pulsed laser irradiation. Interestingly, at high number of laser pulses, Pd and Pt follow different formation pathways, contrary to their common photoreduction mechanism occurring at low irradiation pulses. Specifically, in the case of the Pd, a photofragmentation process takes place fracturing the previously formed nanoparticles into smaller ones; whereas in the case of Pt, the prolonged irradiation promotes the nanoparticles agglomeration. The combination of both precursors in a binary solid system results in the combined formation of both Pd and Pt nanoparticles in the polymer film upon laser irradiation. The herein reported approach is an efficient and precise tool to generate size- and density-controlled Pd and Pt nanoparticles in desired areas of polymeric films, rendering this method a potential candidate for the fabrication of flexible polymeric devices for gas-sensing or electro-catalysis applications. Graphical Abstract: Schematic representation of Pd, Pt and Pd–Pt combined NPs formation mechanisms under pulsed laser irradiation [Figure not available: see fulltext.]