Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.
Allylation of aldehydes by dual photoredox and nickel catalysis / Gualandi A.; Rodeghiero G.; Faraone A.; Patuzzo F.; Marchini M.; Calogero F.; Perciaccante R.; Jansen T.P.; Ceroni P.; Cozzi P.G.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - ELETTRONICO. - 55:48(2019), pp. 6838-6841. [10.1039/c9cc03344k]
Allylation of aldehydes by dual photoredox and nickel catalysis
Gualandi A.
;Rodeghiero G.;Marchini M.;Calogero F.;Ceroni P.
;Cozzi P. G.
2019
Abstract
Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
