The rotational spectra of tert-butanol•••14NH3 and tert-butanol•••15NH3 have been investigated and assigned by pulsed jet Fourier transform microwave spectroscopy. According to the values of the 14N quadrupole coupling constants, the complex (where NH3 acts as a proton acceptor) adopts a configuration with an almost linear O-H•••N hydrogen bond. The NH3 moiety undergoes a nearly free rotation.
A rotational study of the molecular complex tert-butanol•••NH3 / B.M.Giuliano; M.C.Castrovilli; A.Maris; S.Melandri; W.Caminati; E.A.Cohen. - In: CHEMICAL PHYSICS LETTERS. - ISSN 0009-2614. - STAMPA. - 463:(2008), pp. 330-333. [10.1016/j.cplett.2008.08.071]
A rotational study of the molecular complex tert-butanol•••NH3
GIULIANO, BARBARA MICHELA;MARIS, ASSIMO;MELANDRI, SONIA;CAMINATI, WALTHER;
2008
Abstract
The rotational spectra of tert-butanol•••14NH3 and tert-butanol•••15NH3 have been investigated and assigned by pulsed jet Fourier transform microwave spectroscopy. According to the values of the 14N quadrupole coupling constants, the complex (where NH3 acts as a proton acceptor) adopts a configuration with an almost linear O-H•••N hydrogen bond. The NH3 moiety undergoes a nearly free rotation.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
