Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space.
1D and 3D coordination polymers based on the Cu3(μ3-OH)(μ-pz)3 and Cu(Hpz)3 SBUs connected by the flexible glutarate dianion / Forlin, Enrico; Lanza, Arianna; Di Nicola, Corrado; Monari, Magda*; Gazzano, Massimo; Nestola, Fabrizio; Pettinari, Claudio; Pandolfo, Luciano. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 470:(2018), pp. 385-392. [10.1016/j.ica.2017.09.004]
1D and 3D coordination polymers based on the Cu3(μ3-OH)(μ-pz)3 and Cu(Hpz)3 SBUs connected by the flexible glutarate dianion
Monari, Magda
;Gazzano, Massimo;
2018
Abstract
Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
