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EnglishDifferent synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space.
| Titolo: | 1D and 3D coordination polymers based on the Cu3(μ3-OH)(μ-pz)3 and Cu(Hpz)3 SBUs connected by the flexible glutarate dianion |
| Autore/i: | Forlin, Enrico; Lanza, Arianna; Di Nicola, Corrado; Monari, Magda; Gazzano, Massimo; Nestola, Fabrizio; Pettinari, Claudio; Pandolfo, Luciano |
| Autore/i Unibo: | |
| Anno: | 2018 |
| Rivista: | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.ica.2017.09.004 |
| Abstract: | Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space. |
| Data stato definitivo: | 2020-03-02T04:40:26Z |
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