The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.
Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes / M. Bandini; A. Eichholzer; P. Kotrusz; A. Umani-Ronchi. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - STAMPA. - 350:4(2008), pp. 531-536. [10.1002/adsc.200700607]
Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes
BANDINI, MARCO;EICHHOLZER, ASTRID;KOTRUSZ, PETER;UMANI RONCHI, ACHILLE
2008
Abstract
The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.File in questo prodotto:
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