t5-Hydroxymethyl-2-furaldehyde (HMF) is a key bio-based platform for the production of renewablemonomers and bio-fuels. However, most of its syntheses are carried out under not sustainable con-ditions. In this work, the production of HMF from fructose and inulin was investigated following theGreen Chemistry principles, adopting aqueous medium, appreciable substrate concentration (10 wt%),low loading of heterogeneous acid catalyst (niobium or zirconium phosphate) and microwave heating.Both the catalysts resulted very active and promising, in particular zirconium phosphate and the per-formances were related to their different acid characteristics. The optimization of HMF synthesis withzirconium phosphate was also supported by a statistical modelling, which shows that the highest yieldto HMF (about 40 mol%) is ascertained at high temperature (190◦C) and short reaction time (8 min). Thecatalysts resulted recyclable maintaining their starting activity almost unchanged.
Microwave-assisted dehydration of fructose and inulin to HMFcatalyzed by niobium and zirconium phosphate catalysts / Claudia, Antonetti; Mattia, Melloni; Domenico, Licursi; Sara, Fulignati; Erika, Ribechini; Sandra, Rivas; Juan Carlos Parajó, ; Fabrizio, Cavani; Anna Maria Raspolli Galletti,. - In: APPLIED CATALYSIS. B, ENVIRONMENTAL. - ISSN 0926-3373. - STAMPA. - 206:(2017), pp. 364-377. [10.1016/j.apcatb.2017.01.056]
Microwave-assisted dehydration of fructose and inulin to HMFcatalyzed by niobium and zirconium phosphate catalysts
Mattia Melloni;Fabrizio Cavani;
2017
Abstract
t5-Hydroxymethyl-2-furaldehyde (HMF) is a key bio-based platform for the production of renewablemonomers and bio-fuels. However, most of its syntheses are carried out under not sustainable con-ditions. In this work, the production of HMF from fructose and inulin was investigated following theGreen Chemistry principles, adopting aqueous medium, appreciable substrate concentration (10 wt%),low loading of heterogeneous acid catalyst (niobium or zirconium phosphate) and microwave heating.Both the catalysts resulted very active and promising, in particular zirconium phosphate and the per-formances were related to their different acid characteristics. The optimization of HMF synthesis withzirconium phosphate was also supported by a statistical modelling, which shows that the highest yieldto HMF (about 40 mol%) is ascertained at high temperature (190◦C) and short reaction time (8 min). Thecatalysts resulted recyclable maintaining their starting activity almost unchanged.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.