The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
Pulsed jet Fourier transform microwave spectroscopy of the BF3-CO complex
FENG, GANG;GOU, QIAN;EVANGELISTI, LUCA;GRABOW, JENS UWE;CAMINATI, WALTHER
2017
Abstract
The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.File in questo prodotto:
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