Interaction of common imines with WCl6 in organic solvents revealed very unusual features in the context of imine chemistry. Ph2=NH was converted in one pot into the 2-aza-allenium species [Ph2C=N=CPh2]+via N2 release, with [Ph2C=NH2]+ being a co-product. PhCH=NtBu underwent C-H bond activation resulting in the formation of [C≡N] containing derivatives, together with [PhCH=NHtBu]+
One pot conversion of benzophenone imine into the relevant 2-aza-allenium / Bortoluzzi, Marco; Funaioli, Tiziana; Marchetti, Fabio; Pampaloni, Guido; Pinzino, Calogero; Zacchini, Stefano. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 53:2(2017), pp. 364-367. [10.1039/c6cc08702g]
One pot conversion of benzophenone imine into the relevant 2-aza-allenium
ZACCHINI, STEFANO
2017
Abstract
Interaction of common imines with WCl6 in organic solvents revealed very unusual features in the context of imine chemistry. Ph2=NH was converted in one pot into the 2-aza-allenium species [Ph2C=N=CPh2]+via N2 release, with [Ph2C=NH2]+ being a co-product. PhCH=NtBu underwent C-H bond activation resulting in the formation of [C≡N] containing derivatives, together with [PhCH=NHtBu]+I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
