CRIS Current Research Information System
IRIS è la soluzione IT che facilita la raccolta e la gestione dei dati relativi alle attività e ai prodotti della ricerca. Fornisce a ricercatori, amministratori e valutatori gli strumenti per monitorare i risultati della ricerca, aumentarne la visibilità e allocare in modo efficace le risorse disponibili.
EnglishFormic acid and dimethyl ether are combined in a supersonic expansion to form a molecular adduct with the two subunits held together by a "classical" OH⋯O hydrogen bond and a bifurcated weak CH2⋯O hydrogen bond. The rotational spectra of the parent and of two 13C isotopologues in natural abundance show that the complex has Cs symmetry, with the heavy atom symmetry planes of HCOOH and (CH3)2O perpendicular to each other.
| Titolo: | Shape of the Adduct Formic Acid-Dimethyl Ether: A Rotational Study | |
| Autore/i: | EVANGELISTI, LUCA; SPADA, LORENZO; LI, WEIXING; Ciurlini, Anna; Grabow, Jens Uwe; CAMINATI, WALTHER | |
| Autore/i Unibo: | ||
| Anno: | 2016 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/acs.jpca.6b02912 | |
| Abstract: | Formic acid and dimethyl ether are combined in a supersonic expansion to form a molecular adduct with the two subunits held together by a "classical" OH⋯O hydrogen bond and a bifurcated weak CH2⋯O hydrogen bond. The rotational spectra of the parent and of two 13C isotopologues in natural abundance show that the complex has Cs symmetry, with the heavy atom symmetry planes of HCOOH and (CH3)2O perpendicular to each other. | |
| Data stato definitivo: | 2020-02-25T10:22:38Z | |
| Appare nelle tipologie: |
File in questo prodotto:
Eventuali allegati, non sono esposti
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
Copyright © 2021