Electron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations.
Electron attachment to strongly polar clusters: formamide molecule and clusters / M. Seydou ; A. Modelli; B. Lucas; K.Konate; C. Desfrançois; J.P. Schermann. - In: THE EUROPEAN PHYSICAL JOURNAL. D, ATOMIC, MOLECULAR AND OPTICAL PHYSICS. - ISSN 1434-6060. - ELETTRONICO. - DOI:10.1140:(2005), pp. 1-7. [10.1140/epjd/e2005-00089-5]
Electron attachment to strongly polar clusters: formamide molecule and clusters.
MODELLI, ALBERTO;
2005
Abstract
Electron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.