A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.
A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate / G. Bartoli; M. Bosco; A. Carlone; M. Locatelli; E. Marcantoni; P. Melchiorre; P. Palazzi; L. Sambri. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - /:(2006), pp. 4429-4434.
A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate
BARTOLI, GIUSEPPE;BOSCO, MARCELLA;CARLONE, ARMANDO;LOCATELLI, MANUELA;MELCHIORRE, PAOLO;PALAZZI, PAOLO;SAMBRI, LETIZIA
2006
Abstract
A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.File in questo prodotto:
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