Aromatic azides are inert towards triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of additional catalytic amounts of tert-dodecanethiol afford anilinosilanes and thence the corresponding anilines in virtually quantitative yields.
Radical Reduction of Aromatic Azides to Amines with Triethylsilane / M. L. Benati; G. Bencivenni; R. Leardini; M. Minozzi; D. Nanni; R. Scialpi; P. Spagnolo; G. Zanardi. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 71:(2006), pp. 5822-5825. [10.1021/jo060824k]
Radical Reduction of Aromatic Azides to Amines with Triethylsilane
BENATI, MARIA LUISA;BENCIVENNI, GIORGIO;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;ZANARDI, GIUSEPPE
2006
Abstract
Aromatic azides are inert towards triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of additional catalytic amounts of tert-dodecanethiol afford anilinosilanes and thence the corresponding anilines in virtually quantitative yields.File in questo prodotto:
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