Geochemistry of thermal fluids in NW Honduras: New perspectives for exploitation of geothermal areas in the southern Sula graben

The results of a geochemical survey on thermal waters and, for the first time for this site, gas discharges in five geothermal sites (Azacualpa “La Cueva”, Río Ulua, Río Gualcarque, El Olivar and Laguna de Agua Caliente) in NW Honduras are here presented and discussed. El Olivar and Laguna de Agua Caliente, in the southern part of the Sula graben are very close to a Quaternary basaltic field, whereas Azacualpa “La Cueva”, Río Ulua and Río Gualcarque, located to the southwest of the Yojoa Lake, direcly emerge from the Cretaceous limestone deposits. The measured temperatures range between 37.5 and 104.8 °C. “Mature”, alkaline, Na-SO4 thermal waters discharge from Azacualpa “La Cueva”, while those from El Olivar and Laguna de Agua Caliente are “immature” and show a Na-HCO3 composition. Chemical equilibria of waters and gases from the Azacualpa “La Cueva” thermal springs indicate temperatures ranging from 150 to 200 °C. Conversely, gas discharges from El Olivar and Laguna de Agua Caliente have attained a partial chemical equilibrium in the liquid phase at slightly higher temperatures (200–250 °C), although gas–gas faster reactions involving COseemto be adjusted in an isothermally separated vapor phase. Unlike Azacualpa, SiO2 geothermometer at El Olivar and Laguna de Agua Caliente indicates equilibrium temperatures for the liquid phase much lower than those calculated for the gas phase (≤120 °C). We conclude that thermal waters from the Azacualpa area likely represent the direct emergence of a water dominated reservoir having temperatures ≤150–200 °C. By contrast, at El Olivar and Laguna de Agua Caliente hot springs are supplied by a boiling shallow aquifer fed by a vapor phase rising from a steam-dominated zone. The above geochemical model is consistent with a geothermal reservoir hosted within the Cretaceous carbonate sequences of the Yojoa Group in the whole investigated sites. The reservoir extensively crops out in the Azacualpa area whereas the geothermal sites of the southern Sula graben (Laguna de Agua Caliente and El Olivar) are covered by the Oligocene–Miocene volcano–sedimentary sequences of the Matagalpa formation, possibly acting as efficient impermeable cap rocks. These results significantly differ from those reported by previous studies and emphasize that the southern Sula graben, in particular the El Olivar area, can represent among the investigated thermal springs, themost promising site for the exploitation of a high-enthalpy geothermal field.