Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.
A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State / Kalman Toth;Jennifer K. Molloy;Micaela Matta;Benoît Heinrich;Daniel Guillon;Giacomo Bergamini;Francesco Zerbetto;Bertrand Donnio;Paola Ceroni;Delphine Felder-Flesch. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 52:(2013), pp. 12303-12307. [10.1002/anie.201305536]
A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State
MOLLOY, JENNIFER;MATTA, MICAELA;BERGAMINI, GIACOMO;ZERBETTO, FRANCESCO;CERONI, PAOLA;
2013
Abstract
Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
