Geopolymerization is an aqueous based process to produce synthetic alkali-aluminosilicates with porosity that can be tailored from the nano-to the ultra-macrometric range. In order to fulfill the requirements form any different applications and porous 3D networks (name lyalkali- aluminosilicate foams)were prepared by inducing interconnected ultra-macro-porosity(up to the millimeter range) in the alkali-bonded matrices, exploiting the ability of silicon powder to generate H2 in the aqueous medium. Being H2 the product of a water-consuming process which competes with geopolymerization, the process parameters and the characteristics of the resulting foamed materials are strongly influenced by the amount of added silicon. Polymerization degree, accessibility of the geopolymer inner volume and the micro-ultra-macro-structure of the foams were determined and related to the process parameters of the contemporary geopolymerization and foaming.
Effect of metallic Si addition on plymerization degree of in situ foamed alkali-aluminosilicates / V. Medri; E. Papa; J. Dedecek; H. Jirglova; P. Benito; A. Vaccari; E. Landi. - In: CERAMICS INTERNATIONAL. - ISSN 0272-8842. - STAMPA. - 39:(2013), pp. 7657-7668. [10.1016/j.ceramint.2013.02.104]
Effect of metallic Si addition on plymerization degree of in situ foamed alkali-aluminosilicates
BENITO MARTIN, PATRICIA;VACCARI, ANGELO;
2013
Abstract
Geopolymerization is an aqueous based process to produce synthetic alkali-aluminosilicates with porosity that can be tailored from the nano-to the ultra-macrometric range. In order to fulfill the requirements form any different applications and porous 3D networks (name lyalkali- aluminosilicate foams)were prepared by inducing interconnected ultra-macro-porosity(up to the millimeter range) in the alkali-bonded matrices, exploiting the ability of silicon powder to generate H2 in the aqueous medium. Being H2 the product of a water-consuming process which competes with geopolymerization, the process parameters and the characteristics of the resulting foamed materials are strongly influenced by the amount of added silicon. Polymerization degree, accessibility of the geopolymer inner volume and the micro-ultra-macro-structure of the foams were determined and related to the process parameters of the contemporary geopolymerization and foaming.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
