The Fourier transform rotational spectra of the normal and the 13C species of the 1:1 complex between difluoromethane and water have been measured. The rotational transitions are split into two component lines, due to the internal rotation of the water moiety. The barrier to this motion has been estimated to be 340(20) cm 1. An improved structure of the complex has been obtained.
The Fourier transform rotational spectrum of difluoromethane–water: internal motion of water / W. Caminati; S. Melandri; M. Schnell; D. Banser; J.-U. Grabow; J.L. Alonso. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - STAMPA. - 742:(2005), pp. 87-90. [10.1016/j.molstruc.2005.01.014]
The Fourier transform rotational spectrum of difluoromethane–water: internal motion of water
CAMINATI, WALTHER;MELANDRI, SONIA;
2005
Abstract
The Fourier transform rotational spectra of the normal and the 13C species of the 1:1 complex between difluoromethane and water have been measured. The rotational transitions are split into two component lines, due to the internal rotation of the water moiety. The barrier to this motion has been estimated to be 340(20) cm 1. An improved structure of the complex has been obtained.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
