We report unique and spontaneous formation of hydrogels of perylene derivatives with melamine. The luminescent gel network is formed by H-type aggregation of the perylene core, supramolecularly cross-linked by melamine units. As a result of controlled aggregation in the extended nanofibers, strong exciton fluorescence emission is observed.
Assemblies of perylene diimide derivatives with melamine into luminescent hydrogels / P. K. Sukul; D. Asthana; P. Mukhopadhyay; D. Summa; L. Muccioli; C. Zannoni; D. Beljonne; A. E. Rowan; S. Malik. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 47:(2011), pp. 11858-11860. [10.1039/c1cc14189a]
Assemblies of perylene diimide derivatives with melamine into luminescent hydrogels
MUCCIOLI, LUCA;ZANNONI, CLAUDIO;
2011
Abstract
We report unique and spontaneous formation of hydrogels of perylene derivatives with melamine. The luminescent gel network is formed by H-type aggregation of the perylene core, supramolecularly cross-linked by melamine units. As a result of controlled aggregation in the extended nanofibers, strong exciton fluorescence emission is observed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.